松辽盆地西部斜坡区姚家组和四方台组含铀砂岩地球化学特征

    Geochemistry of uranium-bearing sandstones of Yaojia Formation and Sifangtai Formation in the western slope of Songliao Basin

    • 摘要: 对松辽盆地西部斜坡区姚家组和四方台组含铀地层沉积环境、构造背景、物源及其与成矿关系开展研究, 对6个代表性钻孔中的30个样品进行主量元素、微量元素和稀土元素进行分析测试. 结果表明, 赋矿碎屑岩以长石岩屑砂岩为主, 具有SiO2含量变化较大(38.94%~83.32%, 平均为73.07%)、富碱(Na2O+K2O 4.47%~6.78%)、铝含量较高(Al2O3 8.15%~13.55%, 平均为11.46%)、镁钙含量相对较高(MgO 0.18%~7.38%, 平均为0.88%; CaO 0.17%~12.63%, 平均为1.96%)的特征. 稀土总量较低(ΣREE 70.08×10-6~211.33×10-6)、轻稀土分馏系数(La/Sm)N=2.32~3.96, 重稀土分馏系数(Gd/Yb)N=1.54~3.25, Eu为中等负异常(δEu=0.60~0.90), 壳源岩浆特征明显. 砂岩的ICV值(0.54~2.30, 平均值为0.84)和CIA值(41.08~68.96, 平均值为61.77)反映出源区干旱-半干旱气候条件下的中等化学风化作用. 源岩属性判别图解表明源岩以长英质岩石为主, 并且含少量古老沉积物质. 主量元素和微量元素的构造背景判别图解综合表明姚家组、四方台组砂岩物源区为主动大陆边缘的构造环境, 物源为大兴安岭地区发育的酸性火成岩-沉积岩系.

       

      Abstract: The paper comprehensively studies the sedimentary environment, tectonic setting, provenance, and their relationship with uranium mineralization in the uranium-bearing strata of Yaojia Formation and Sifangtai Formation in the western slope of Songliao Basin, and analyzes the major, trace, and rare earth elements (REEs) in 30 samples from six representative boreholes. The results show that the ore-hosting clastic rocks are predominantly feldspar lithic sandstone, characterized by various SiO2 contents, rich alkali, and high contents of Al, Mg and Ca, with low ΣREE (70.08×10-6-211.33×10-6), LREE fractionation factor(La/Sm)N of 2.32-3.96, HREE fractionation factor(Gd/Yb)N of 1.54-3.25, and moderately negative Eu anomaly. The index of compositional variability (ICV) (0.54-2.30, averagely 0.84) and chemical index of alteration (CIA) values (41.08-68.96, averagely 61.77) of the sandstone reflect moderate chemical weathering in the source area under arid to semi-arid climatic conditions. The discrimination diagrams of source rock indicate that the provenance is dominated by felsic rocks, with minor contributions from ancient sedimentary materials. The discrimination diagrams of major and trace elements suggest that the sandstones of Yaojia and Sifangtai formations are derived from the active continental margin tectonic setting, with provenance primarily from the acidic igneous-sedimentary rock series developed in Daxinganling Mountains.

       

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